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[TheDreadPirate]

You need to remove the backslashes on the quotes.  Parenthesis are fine as long as they are escaped or in quotes.  Since the quotes are escaped they are not treated as actual quotes, therefore not putting the parenthesis in quotes.  Also, why are you ffprobe-ing a subtitle file?

ffprobe will just dump a bunch of text.  You can either scroll and copy and paste or output it into a text file.

Code:

/usr/lib/jellyfin-ffmpeg/ffprobe -analyzeduration 200M -probesize 1G -i file:"/mnt/Syno-Lenovo-1/Videos/_English/The Kids Are All Right (2010)/The.Kids.Are.All.Right.2010.720p.BluRay.x264.YIFY.srt" -threads 0 -v warning -print_format json -show_streams -show_format > output.txt 2>&1

Can you run this command and share the output?

Code:

ls -ld /mnt/Syno-Lenovo-1 /mnt/Syno-Lenovo-1/Videos /mnt/Syno-Lenovo-1/Videos/_English /mnt/Syno-Lenovo-1/Videos/_English/"The Kids Are All Right (2010)"
ls -l /mnt/Syno-Lenovo-1/Videos/_English/"The Kids Are All Right (2010)"/*